By Lars Ernster
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Additional info for Bioenergetics New Comprehensive Biochemistry
1965) Trans. 21, 1897-1911. Katchalsky, A. F. (1967, 1974 2nd) Non-Equilibrium Thermodynamics in Biophysics. Harvard University Press, Cambridge, MA. R. and Essig, A. ) pp. 165-191, Interscience, New York. F. V. (1982) Trends Biochem. Sci. 7, 275-279. R. and Kedem, 0. (1967) Biophys. J. 7, 735-757. V. and Van Dam, K. (1979) Curr. Top. Bioenerg. 9, 1-62. 9 Nicolis, G. and Prigogine, I. (1977) Self-organization in Nonequilibrium Systems. Wiley and Sons, New York. 10 Keizer, J. (1975) J. Theor. Biol.
Hence, the quality of the linear approximation is even more impressive in terms of the velocity range for which it is valid: with a deviation of less than 15% the following equation describes 75% of the range of the reaction rate: 1 u = - 4RT ('s + 'P ' ( p s - I*P ,) - f ('s + 'P ' In( 'S/'P) + ( vs - 'P (22) Here: and According to enzyme kinetics vs and - v p are the reaction rates when [PI = 0, or [S] = 0, respectively. , ( vs + vP)/4RT) depends on the kinetic constants and the sum concentration of 10 substrate and product.
And Kunz, W. (1976) Biochim. Biophys. Acta 440,391-402. , Otto, R. J. (1982) Biochim. Biophys. Acta 683, 181-220. J. and Van Dam, K. (1981) Proc. Natl. Acad. Sci. A. 78, 3554-3558. V. and Van Dam, K. (1984) Mosaic Non-Equilibrium Thermodynamics of (the Control of) Energy Metabolism. Elsevier, Amsterdam, in the press. M. and Van den Berg, G. , Quagliariello, E. Siliprandi, N. ) pp. 389-397, Elsevier, Amsterdam. W. & Walz, D. (1982) Eur. J. Biochem. 127, 483-494. 27 Walz, D. (1983) In Biological Structures and Coupled Flows (Oplatka, A.
Bioenergetics New Comprehensive Biochemistry by Lars Ernster